Salt bath nitriding

Salt bath nitriding is a physiochemical process. It increases the hardness of a component surface by treating it in a nitriding bath (salt melt) with subsequent oxidation in a quenching bath. The characteristics of the surface can be further enhanced by polishing (blasting) During salt bath nitriding, the workpiece is enriched only with nitrogen. The process of salt bath nitrocarburising (Tenifer process) also treats the workpieces with carbon in addition to nitrogen. You can commission both processes from us. No matter whether you require salt bath nitriding or a different state-of-the-art process: we will optimise even the most challenging technical components for you. As a single part, in custom sizes, or as volume production - whatever your requirements are. Feel free to contact us for a personal, no-obligation consultation.

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The process and its advantages

Salt bath nitriding starts off with a heat treatment of the workpieces at approx. 350°C. This treatment is followed up with the creation of a protective diffusion zone in a 580 °C nitriding bath consisting of a salt melt. During this treatment, both nitrogen and carbon penetrate the surface of the component.
 
To attain the desired properties, the cyanide/cyanate content of the salt melt is regulated. The duration of the treatment may vary between a few minutes to several hours, depending on the type of steel. Once the treatment time has elapsed, water, oil, or a polymer are used to quench the workpieces.
 

Post-treatment in an oxidation bath: Tenifer QPQ process


During the Tenifer QPQ process, after the nitriding bath the workpieces are immersed in an oxidation bath. The cyanide clinging to the workpieces is neutralised at 380°C. This process takes between 10 and 15 minutes. The workpieces are then quenched with water. Tenifering produces an extremely high level of corrosion resistance, frequently surpassing even galvanic edge layers. In addition, the workpieces gain a refined blackened surface.
 

The advantages of salt bath nitriding/salt bath nitrocarburising at a glance

  • Improved resistance to wear and corrosion
  • Increased fatigue resistance
  • Pleasing aesthetics of the components thanks to blackening oxidation
  • Minimum warping makes reworking the components unnecessary
  • Reliably reproducible results
  • Short treatment times
  • The nitrided layer is heat-resistant up to 600°C
  • Partial hardening possible
  • High-alloy and high-chromium steels can also be treated

Areas of application

In general, all grades of steel are suitable for salt bath nitriding. However, certain alloy steels are especially suitable for this process. The process is a particular favourite in mechanical engineering and the automotive industry.
 

Summary: Typical real-world applications

  • Mechanical and apparatus engineering
  • Vehicle construction
  • Precision engineering
  • Automotive industry

 

Summary: Which materials are suitable?

  • Steel materials
  • Cast materials
  • Sintered materials
  • Non-alloy materials
  • Low-alloy materials
  • Medium-alloy materials

Check list: Ordering salt bath nitriding

If you would like us to treat your workpieces or materials with a salt bath nitriding process, we will gladly advise you on the best procedure. You can use the check list below to make your preparations for the order.

     

  • Which material is to be treated, and what is its condition?
  • What is the target hardness (including tolerance range in HV)?
  • What is the desired nitriding hardness depth (including tolerance range in mm)?
  • If applicable, which areas are to be salt bath nitrided, and where can the hardness be measured?
  • If applicable, how thick should the compound layer be (including tolerance range in μm)?

Note:
We use a sample that we take ourselves to measure the thickness of the compound layer and/or the nitriding hardness depth. For measurements that are specifically related to your order, we need you to provide us with a reference component that is intended for the hardening treatment.

Surface hardness and nitriding hardness depth of various materials

You can see which surface hardnesses can be achieved in the material table at the bottom of the page.
 
The maximum hardness ultimately depends on the material used. All information subject to change.
 
PDF
 
https://www.lingenhoele.at/wp-content/uploads/Lingenhoele_Werkstoffkennwerte_Nitrieren.pdf

Process locations

We offer state-of-the-art salt bath nitriding processes at the following locations: location overview

Suitable materials

Select material table
    Unalloyed steel
    Tempered steel
    Case hardening steel
    Nitriding steel
    Ball bearing steel
    Grey cast iron - nodular cast iron
    Stainless steel
    Cold-work steel
    Hot working steel
    High-speed steel (HSS)
DIN EN 10027-2 Material numberDIN EN 10027-2 Short nameVickers surface hardness (HV0,5)Max. nitriding hardness depth NHD [mm]
1.1960E335280-5000,6
1.0577$355280-4800,6
1.1191C45 E300-5000,7
1.1221C 60 E300-5000,7
1.512237MnSI5300-5000,6
DIN EN 10027-2 Material numberDIN EN 10027-2 Short nameVickers surface hardness (HV0,5)Max. nitriding hardness depth NHD [mm]
1.076244SMn28 (ETG 100)400-5000,3
1.703334Cr4500-6000,5
1.722034CrMo4500-6000,5
1.7225/1.7227 42CrMo4/42CrMoS4550-7000,5
1.815950Crv4550-7000,5
1.816158CrV4550-7000,5
1.658234CrNiMo6600-8000,5
1.271045NIC16600-7500,4
1.231240CrMnMo586650-8000,3
DIN EN 10027-2 Material numberDIN EN 10027-2 Short nameVickers surface hardness (HV0,5)Max. nitriding hardness depth NHD [mm]
1.7131/1.713916MnCr5/16MnCr$5600-7500,5
1.714720MnCr5600-6500,4
1.575214NiCr14500-6500,4
DIN EN 10027-2 Material numberDIN EN 10027-2 Short nameVickers surface hardness (HV0,5)Max. nitriding hardness depth NHD [mm]
1.850434CA16900-12000,4
1.850734CrAIM05900-13000,5
1.851931 CrMoV9780-9000,5
1.855034CrAIN17900-11000,5
DIN EN 10027-2 Material numberDIN EN 10027-2 Short nameVickers surface hardness (HV0,5)Max. nitriding hardness depth NHD [mm]
1.3505100Cr6450-7000,25
1.2510100MnCrW4500-7000,25
DIN EN 10027-2 Material numberDIN EN 10027-2 Short nameVickers surface hardness (HV0,5)Max. nitriding hardness depth NHD [mm]
6.025EN-GJL-250 (GG 25)300-4500,3
7.080EN-GJS-600 (GGG 60)450-6000,4
DIN EN 10027-2 Material numberDIN EN 10027-2 Short nameVickers surface hardness (HV0,5)Max. nitriding hardness depth NHD [mm]
1.4006X10Cr13900-11000,1
1.4021X20Cr13900-12000,1
1.4034X40Cr13900-12000,1
1.4122X35CrBo171000-12500,15
1.4571X10CN/MoTI1712-2900-11500,1
DIN EN 10027-2 Material numberDIN EN 10027-2 Short nameVickers surface hardness (HV0,5)Max. nitriding hardness depth NHD [mm]
1.2379X155CrMoV121900-12000,15
1.2080X210Cr12850-11500,15
1.2364X100CrMoV511000-12000,2
1.2601X165CrMoV12900-11500,15
1.2436X210CrV12700-9000,15
DIN EN 10027-2 Material numberDIN EN 10027-2 Short nameVickers surface hardness (HV0,5)Max. nitriding hardness depth NHD [mm]
1.2343X38CrMoV51900-11500,4
1.2343X40CrMoV51900-11500,4
1.2567X30WCrV53850-10500,3
1.2365X32CrMoV33750-9000,3
1.2436X210CrV12700-9000,15
DIN EN 10027-2 Material numberDIN EN 10027-2 Short nameVickers surface hardness (HV0,5)Max. nitriding hardness depth NHD [mm]
All qualities950-14000,02-0,15

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